maddie6825
27.02.2020 •
Chemistry
A buffer with a pH of 4.31 contains 0.31 M of sodium benzoate and 0.24 M of benzoic acid. What is the concentration of [ H 3 O ] in the solution after the addition of 0.060 mol HCl to a final volume of 1.3 L
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Ответ:
The hydronium ion concentration in the solution is
Explanation:
To calculate the molarity, we use the equation:
Moles hydrochloric acid solution = 0.060 mol
Volume of solution = 1 L
Putting values in above equation, we get:
The chemical reaction for aniline and HCl follows the equation:
Initial: 0.24 0.060 0.31
Final: 0.18 - 0.37
To calculate the pH of acidic buffer, we use the equation given by Henderson Hasselbalch:
We are given:
= negative logarithm of acid dissociation constant of benzoic acid = 4.2
pH = ?
Putting values in equation 1, we get:
To calculate the hydronium ion concentration in the solution, we use the equation:
pH = 3.89
Putting values in above equation, we get:
Hence, the hydronium ion concentration in the solution is
Ответ: