Calculate the freezing point of a solution containing 25 grams of kcl and 2750.0 grams of water. the molal freezing point depression constant (kf) for water is 1.86 ∘c/m.1.23 oc-0.45 oc+0.45 oc-0.23 oc+0.23 oc
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Ответ:
-0.45 °C
Explanation:
The freezing point depression can be calculated using the formula:
ΔT=Kf * b * iWhere ΔT is the change of the freezing point temperature (from 0°C of pure water), Kf is 1.86 °C/m, b is the molality, and i is 2 (in this case with KCl).
All data required is given except for b, so we calculate the molality:
molality = moles solute / kilograms of solvent25 g KCl ÷ 74.55g/mol = 0.3353 mol KCl
2750 g water ⇒ 2750/1000 = 2.75 kg water
molality = 0.3353/2.75 = 0.1219 mNow we calculate ΔT:
ΔT = 1.86 °C/m * 0.1219 m * 2ΔT = 0.45 °CSo the freezing point of the solution is [0°C - 0.45°C] = -0.45 °C
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