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23.01.2021 •
Chemistry
Calculate the second volumes. 955 L at 58 C and 108 KPa to 76 C and 123 KPa
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Ответ:
The second volume : V₂= 884.14 L
Further explanationGiven
955 L at 58 C and 108 KPa
76 C and 123 KPa
Required
The second volume
Solution
T₁ = 58 + 273 = 331 K
P₁ = 108 kPa
V₁ = 955 L
P₂ = 123 kPa
T₂ = 76 + 273 = 349
Use combine gas law :
P₁V₁/T₁ = P₂V₂/T₂
Input the value :
108 x 955/331 = 123 x V₂/349
V₂= 884.14 L
Ответ:
The question is incomplete, here is the complete question:
When a lead acid car battery is recharged by the alternator, it acts essentially as an electrolytic cell in which solid lead(II) sulfate PbSO₄ is reduced to lead at the cathode and oxidized to solid lead(II) oxide PbO at the anode.
Suppose a current of 96.0 A is fed into a car battery for 37.0 seconds. Calculate the mass of lead deposited on the cathode of the battery. Round your answer to 3 significant digits. Also, be sure your answer contains a unit symbol.
The mass of lead deposited on the cathode of the batter is 3.81 grams
Explanation:
To calculate the charge deposited, we use the equation:
We are given:
Current supplied = 96.0 A
Time = 37.0 seconds
Putting values in above equation, we get:
We know that:
96500 C of charge deposition is contained in 1 mole of electrons
So, 3552 C of charge deposition will be contained in =
of electrons
The half reaction follows:
At cathode:![Pb(aq.)+2e^-\rightarrow Pb(s)](/tpl/images/0553/0404/a0b88.png)
Number of electrons exchanged are 2
So, moles of lead deposited =![\text{Number of moles of electrons}}{\text{Number of electrons}}=\frac{0.0368}{2}=0.0184mol](/tpl/images/0553/0404/0badc.png)
To calculate the number of moles, we use the equation:
Molar mass of lead = 207.2 g/mol
Moles of lead = 0.0184 moles
Putting values in above equation, we get:
Hence, the mass of lead deposited on the cathode of the batter is 3.81 grams