cuppykittyy
22.10.2019 •
Chemistry
Ethanol (ch3ch2oh), the intoxicant in alcoholic beverages, is also used to make other organic compounds. in concentrated sulfuric acid, ethanol forms diethyl ether and water: 2ch3ch2oh(l) → ch3ch2och2ch3(l) + h2o(g) in a side reaction, some ethanol forms ethylene and water: ch3ch2oh(l) → ch2═ch2(g) + h2o(g) a) if 50.0 g of ethanol yields 35.9 g of diethyl ether, what is the percent yield of diethyl ether? b) during the process, 45.0% of the ethanol that did not produce diethyl ether reacts by the side reaction. what mass of ethylene is produced?
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Ответ:
a) 88.48%
b) 0.05625 mol
Explanation:
2CH₃CH₂OH(l) → CH₃CH₂OCH₂CH₃(l) + H₂O(g) Reaction 1
CH₃CH₂OH(l) → CH₂═CH₂(g) + H₂O(g) Reaction 2
a) CH₃CH₂OH = 46.0684 g/mol
CH₃CH₂OCH₂CH₃ = 74.12 g/mol
1 mol CH₃CH₂OH 46.0684 g
x 50.0 g
x = 1.085 mol CH₃CH₂OH
1 mol CH₃CH₂OCH₂CH₃ 74.12 g g
y 35.9 g
y = 0.48 mol CH₃CH₂OCH₂CH₃
100% yield 0.5425 mol CH₃CH₂OCH₂CH₃
w 0.48 mol CH₃CH₂OCH₂CH₃
w = 88.48%
b) Only 0.96 mol of ethanol reacted to form diethyl ether. This means that 0.125 mol of ethanol did not react. 45% of 0.125 mol reacted to form ethylene. Therefore, 0.05625 mol of ethanol reacted by the side reaction (reaction 2). Since 1 mol of ethanol leads to 1 mol of ethylene, 0.05625 mol of ethanol produces 0.05625 mol of ethylene.
Ответ:
1. they vary with a higher number because boiling is way hotter than melting