stephaniero6
26.11.2019 •
Chemistry
One of the many reactions which occur when iron ore is smelted in a blast furnace is given below. for this reaction, the equilibrium constant in terms of partial pressures, kp, is 0.900 at 873 k and 0.396 at 1273 k. assume the reaction takes place in a vessel containing only product and reactant molecules and that ah and as do not change with temperature. feo(s) + co(g) = fe(s) + co2(g) a) calculate ah, ag and as for the reaction at 873 k b) what is the mole fraction of co2(g) at 873 k? include only the gas-phase species in this mole fraction.
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Ответ:
Explanation: AH, AG and AS for the reaction at 873 K
delta G =-RT ln Kp
G= -8.314 x 873 ln 0.9
= 764.7J/mol
AG = AH-TAS
AH = 764.7 - 8314(0.9)
Kp =pCO/pCo2
Substitute the values at different temp. Solve simultaneously
Since mole fraction =kp/pCo
Mf =1.5
Ответ: