lilkassrocks
lilkassrocks
18.04.2021 • 
Chemistry

QUESTION 2 Given that
as
ди
ar
Derive an expression for (as/OV), for n moles of a gas obeying the truncated virial equation of
state
PV = 1+
В. В.
V V
RT
where S is entropy, V is volume, p is pressure, T is temperature, R is the ideal gas constant, Vm is
molar volume, B2 and B; are virial coefficients that depend on temperature T. Suppose B3 = 0, B2 =
-15.8x100 m moll and dB2/dt = 0.25x10 mmol K-, evaluate this expression for 1 mole of
argon in 25 cm at 303.15 K.​

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