Solid NaI is slowly added to a solution that is 0.0079 M Cu+ and 0.0087 M Ag+.Which compound will begin to precipitate first?NaICuIAgICalculate [Ag+]when CuI just begins to precipitate.×10MEnter your answer in scientific notation.What percent of Ag+ remains in solution at this point?
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Ответ:
Answer :
AgI should precipitate first.
The concentration of
when CuI just begins to precipitate is, ![6.64\times 10^{-7}M](/tpl/images/0586/7144/7a7c7.png)
Percent of
remains is, 0.0076 %
Explanation :
As we know that these two salts would both dissociate in the same way. So, we can say that as the Ksp value of AgI has a smaller than CuI then AgI should precipitate first.
Now we have to calculate the concentration of iodide ion.
The solubility equilibrium reaction will be:
The expression for solubility constant for this reaction will be,
Now we have to calculate the concentration of silver ion.
The solubility equilibrium reaction will be:
The expression for solubility constant for this reaction will be,
Now we have to calculate the percent of
remains in solution at this point.
Percent of
remains = ![\frac{6.64\times 10^{-7}}{0.0087}\times 100](/tpl/images/0586/7144/8fcb7.png)
Percent of
remains = 0.0076 %
Ответ: