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unknown235
10.12.2019 •
Chemistry
The 1h nmr signal for bromoform (chbr3) appears at 2065 hz when recorded on a 300−mhz nmr spectrometer. if the spectrum was recorded on a 200−mhz instrument, what would be the chemical shift of the chbr3 proton? enter your answer in the provided box.
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Ответ:
The chemical shift (δ) for CHBr₃ proton = 6.88 ppm
Explanation:
In NMR spectroscopy, Chemical shift (δ) is expressed in parts per million (ppm) and is given by the equation:
Given: Observed frequency: ν₁ = 2065 Hz,
Spectrometer frequency: ν'₁ = 300 MHz, ν'₂ = 200 MHz
To calculate the chemical shift (δ) for the given CHBr₃ proton, we use the equation (1)
Since in NMR spectroscopy, chemical shift is a field independent scaling. Thus the value of the chemical shift of a given proton, such as CHBr₃ proton, is independent of the magnetic field strength of the spectrometer.
So the value of chemical shift of a given proton remains same when measured with a 300 MHz and 200 MHz NMR spectrometer.
Therefore, the chemical shift (δ) for CHBr₃ proton = 6.88 ppm
Ответ: