Chemistry: When do th macroscopic properties become constant in an equilibrium system?

When do th macroscopic properties become constant

gloriahope3017

17.06.2020

Explanation:

To calculate pH you need to use Henderson-Hasselbalch formula:

pH = pka + log₁₀ $\frac{[A^-]}{[HA]}$

Where HA is the acid concentration and A⁻ is the conjugate base concentration.

The equilibrium of acetic acid is:

CH₃COOH ⇄ CH₃COO⁻ + H⁺ pka: 4,75

Where CH₃COOH is the acid and CH₃COO⁻ is the conjugate base.

Thus, Henderson-Hasselbalch formula for acetic acid equilibrium is:

pH = 4,75 + log₁₀ $\frac{[CH_{3}COO^-]}{[CH_{3}COOH]}$

a) The pH is:

pH = 4,75 + log₁₀ $\frac{[2 mol]}{[2 mol]}$

pH = 4,75

b) The pH is:

pH = 4,75 + log₁₀ $\frac{[2 mol]}{[1mol]}$

pH = 5,05

I hope it helps!

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