A possible reaction of ethane with chlorine is:
CH3CH3 + Cl2 ---> CH3CH2Cl + HCl
This reaction could conceivably occur by the following chain mechanism involving steps [1], [2], [3] and [4]. The chain initiating step(s) is (are):
[1] Cl2 --> 2Cl*
[2] Cl* + CH3CH3 --> HCl + CH3C*H2
[3] CH3C*H2 + Cl2 ---> CH3CH2Cl + Cl*
[4] Cl* + Cl* ---> Cl2
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