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mvtthewisdead
01.02.2020 •
Chemistry
Abomb calorimeter, or a constant volume calorimeter, is a device often used to determine the heat of combustion of fuels and the energy content of foods. in an experiment, a 0.9973 g sample of isophthalic acid (c8h6o4) is burned completely in a bomb calorimeter. the calorimeter is surrounded by 1.319×103 g of water. during the combustion the temperature increases from 25.37 to 28.49 °c. the heat capacity of water is 4.184 j g-1°c-1. the heat capacity of the calorimeter was determined in a previous experiment to be 939.3 j/°c. assuming that no energy is lost to the surroundings, calculate the molar heat of combustion of isophthalic acid based on these data.
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Ответ:
find heat released by the burn:
(2 g) (19.4 kJ/g) = 38.8 kJ released
find heat gained by the water:
dH = m C dT
dH = (2250 g) (4.184 J/g-C) (+ 3.17 C)
dH = 29,842 Joules
aka
dH water = + 29.8 kJ
find the missing heat given to the calorimeter
(38.8 kJ released) - (29.8 kJ given to water) = 9.0 kJ given to calorimeter
What is the heat capacity of the empty bomb calorimeter
(9.0 kJ given to calorimeter) / (3.17 C rise in temp) = 2.84 kJ / C
Ответ: