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barbiegirllover
02.12.2020 •
Chemistry
. Consider the following half-reactions:
Ag+(aq) + e– → Ag(s) E = +0.80 V
Cu2+(aq) + 2 e– → Cu(s) E = +0.34 V
Pb2+(aq) + 2 e– → Pb(s) E = –0.13 V
Fe2+(aq) + 2 e– → Fe(s) E = –0.44 V
Al3+(aq) + 3 e– → Al(s) E = –1.66 V
Which of the above metals or metal ions will reduce Pb2+(aq)?
a. Ag+(aq) and Cu2+(aq)
b. Ag(s) and Cu(s)
c. Fe2+(aq) and Al3+(aq)
d. Fe(s) and Al(s)
e. Cu2+(aq) and Fe2+(aq)
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Ответ:
d. Fe(s) and Al(s)
Further explanationIn the redox reaction, it is also known
Reducing agents are substances that experience oxidation
Oxidizing agents are substances that experience reduction
The metal activity series is expressed in voltaic series
Li-K-Ba-Ca-Na-Mg-Al-Mn- (H2O) -Zn-Cr-Fe-Cd-Co-Ni-Sn-Pb- (H) -Cu-Hg-Ag-Pt-Au
The more to the left, the metal is more reactive (easily release electrons) and the stronger reducing agent
The more to the right, the metal is less reactive (harder to release electrons) and the stronger oxidizing agent
So that the metal located on the left can push the metal on the right in the redox reaction
The electrodes which are easier to reduce than hydrogen (H), have E cells = +
The electrodes which are easier to oxidize than hydrogen have a sign E cell = -
So the above metals or metal ions will reduce Pb²⁺ (aq) will be located to the left of the Pb in the voltaic series or which have a more negative E cell value (greater reduction power)
The metal : d. Fe(s) and Al(s)
Ответ:
i believe the answer is true.