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19.03.2020 •
Chemistry
Determine the point groups for a. Ethane (staggered conformation) b. Ethane (eclipsed conformation) c. Chloroethane (staggered conformation) d. 1,2-Dichloroethane (staggered anti conformation)
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Ответ:
Answer and Explanation:
Every molecule has a set of symmetry operations that helps in determining its overall symmetry. This set of operations determines the point group of a molecule.
(a) Ethane (staggered conformation)
Ethane in the staggered conformation has:
twohence the point group of ethane in staggered conformation is![D_{3d}](/tpl/images/0552/9986/dc1c5.png)
(b) Ethane (eclipsed conformation)
Ethane in the eclipsed conformation has:
twoHence the point group of ethane in eclipsed conformation is![D_{3h}](/tpl/images/0552/9986/75d1c.png)
(c) chloroethane (staggered conformation)
Chloroethane in the staggered conformation has:
no rotational axis σ plane containing two carbons and chlorine and the anti hydrogen of ClHence the point group of staggered conformation in chloroethane is![C_{s}](/tpl/images/0552/9986/e266f.png)
(c) 1,2-Dichloroethane (staggered anti conformation)
1,2-Dichloroethane in the staggered anti conformation has:
Hence the point group in the staggered anti conformation of 1,2-Dichloroethane is![C_{2h}](/tpl/images/0552/9986/52649.png)
Ответ: