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01.12.2020 •
Chemistry
Explain how mixture melting points can be helpful in distinguishing between two compounds that have essentially the same melting point.
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Ответ:
Ответ:
OH⁻ < NH₃ < HCO₃⁻ < H₂O < NH₄⁺ < H₂CO₃
Explanation:
We can do some rough calculations to find the approximate pH values of these solutions.
H₂CO₃
Kₐ ≈ 10⁻⁶
NH₄⁺
Kb of NH₃ ≈ 10⁻⁵
Kₐ of NH₄⁺ ≈ 10⁻⁹
OH⁻
Strong base
[OH⁻] = 10⁻¹
pOH = 1
pH = 14 - 1 = 13
HCO₃⁻
Salt of dibasic acid
K₁ ≈ 10⁻⁶; K₂ ≈ 10⁻¹⁰
NH₃
Kb ≈ 10⁻⁵
pOH = 14 - 3 = 11
H₂O
Neutral. pH = 7
Order from lowest [H₃O⁺] to highest [H₃O⁺]:
OH⁻ < NH₃ < HCO₃⁻ < H₂O < NH₄⁺ < H₂CO₃
pH 1 3 11 8 7 5 3.5