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UaRemomGAY
30.04.2021 •
Chemistry
For the following reactions, predict the products, phases, and balance the chemical reactions,
6)
NaBr (aq) +
H3PO4 (aq) →
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Ответ:
(Chemical compound and indicated bond in attachment).
C) This is a triple bond between two carbons in which a sigma bond arises from sp- sp overlap and two pi bonds are formed by side-to-side overlap of unhybridized p orbitals on each carbon.
Explanation:
Alkynes are hydrocarbons that contain carbon-carbon triple bonds. Each carbon atom is bound to the other two atoms, and there are no free valence electrons. Each carbon atom needs two hybrid orbitals to form the skeleton of sigma bonds. The hybridization of the s orbital with a p orbital generates two hybrid orbitals, oriented at 180º of separation for each carbon atom. The overlap of these hybrid orbitals sp with the s orbitals from the hydrogen produces the skeleton of sigma bonds.
The result of the overlap of the two remaining unhybridized p orbitals of each atom of carbon is the formation of two pi bonds. These orbitals overlap in right angles with each other, forming a pi bond with electronic density above and below the sigma bond and the other with electronic density in front of and behind the sigma bond. The form of these pi bonds is such that they combine to form a cylinder of electron density that "wraps" the sigma bond between the two carbon atoms.