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chmereaustin1
21.05.2020 •
Chemistry
Suppose the decomposition of nitrogen dioxide proceeds by the following mechanism:
step elementary reaction rate constant
1 NO2 (g) → NO (g) + O (g) k1
2 O (g) + NO2 (g) → O2 (g) + NO (g) k2
Suppose also k1>>k2. That is, the first step is much faster than the second.
(a) Write the balanced chemical equation for the overall chemical reaction.
(b) Write the experimentally-observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates.
(c) Express the rate constant k for the overall chemical reaction in terms of k1, k2, and (if necessary) the rate constants k.1 and k.2 for the reverse of the two elementary reactions in the mechanism.
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Ответ:
The concentration (in mM units) of vitamin C in the juice is 0.64mM.
Explanation:
Let us calculate -:
Concentration of sample =>![1ml\times 29.4mM](/tpl/images/0847/5685/07ff4.png)
= 29.4 mmol => 29.4mmol/50ml
= 0.588mM
plug in formula =>
or
= [2.02 micro-Amber/3.79micro-Amber]
plug in and simplify
1.81x = 1.17
x = 0.64mM
Hence , the answer is 0.64mM.