The active ingredient in aspirin is acetylsalicylic acid. a 2.51-g sample of acetylsalicylic acid required 27.36 ml of 0.5106 m naoh for complete reaction. addition of 13.68 ml of 0.5106 m hcl to the flask containing the aspirin and the sodium hydroxide produced a mixture with ph = 3.48. determine the molar mass of acetylsalicylic acid and its ka value. state any assumptions you must make to reach your answer.

Hey there!

mass of sample = 2.51 g of Aspirin

Number of moles of base  ( NaOH ) :

M*V = 27.36*0.5106 = 13.9700 mmol of base

M*V = 13.68*0.516 = 7.05888 mmol of acid

pKa calculation:

pH = pKa + log(A-/HA)

3.48 = pKa + log(7.05888 / (13.9700 -7.05888))

Pka =3.49 -  log(7.05888 / (13.9700 -7.05888))

pKa = 3.48

Molar mass calculation:

molar mass = mass/mol

(2.51)/(13.9700 *10⁻³) =

molar mass 180 g/mol approx

Hope that helps!

The new volume of the car tire is approximately 11.784 litres

Explanation:

The initial pressure of the air in the car tire, P₁ = 2.18 atm

The volume occupied by the air in the tire, V₁ =  10.0 L

The new pressure of the air in the tire, P₂ = 1.85 atm.

According to Boyle's Law, we have;

P₁·V₁ = P₂·V₂

Where;

P₁ = The initial pressure of the car tire = 2.18 atm

V₁ - The initial volume of the tire = 10.0 L

P₂ = The new pressure of the tire = 1.85 atm

V₂ = The new volume of the car tire = The required volume

Therefore;

Plugging in the values gives;

The new volume of the car tire, V₂ ≈ 11.784 L.