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yentel110306
11.05.2021 •
Chemistry
When a container is filled with 8 moles of H2,7 moles of O2, and 2 mole of N2, the pressure in the container is 10.6 atm. Find Po2
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Ответ:
ΔG = -24.7kJ/mol
Explanation:
ΔG° of
Pb2+(aq) + 2Br-(aq) ⇄ PbBr2(s)
is:
ΔG° PbBr2 - (2*ΔG°Br- + ΔG°Pb2+)
-261.9kJ/mol - (2*-104.0kJ/mol + -24.4kJ/mol) =
-29.5kJ/mol
ΔG of the reaction is:
ΔG = ΔG° + RT lnQ
Where R is gas constant (8.314x10⁻³kJ/molK)
T is absolute temperature (20°C + 273.15 = 293.15K)
Q is reaction quotient = 1 / [Pb²⁺][Br⁻]²
Replacing:
ΔG = -29.5kJ/mol + 8.314x10⁻³kJ/molK*293.15K ln(1 / [Pb²⁺][Br⁻]²)
ΔG = -29.5kJ/mol + 8.314x10⁻³kJ/molK*293.15K ln(1 / [0.247M][0.758M]²)
ΔG = -24.7kJ/mol