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Hannahmiller3773
16.08.2020 •
Chemistry
Which one of the following reactions would produce t-butyl methyl ether in high yield?
A) t-butyl chloride + sodium methoxide
B) t-butanol + methanol in presence of H2SO4 at 140 C
C) t-butyl bromide + bromomethane in presence of NaOH
D) sodium t-butoxide + bromomethane
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Ответ:
D) sodium t-butoxide + bromomethane
Explanation:
The alkoxide ion is a strong nucleophile, that unlike alcohols, will react with primary alkyl halides to form ether. This general reaction is known as the Williamson synthesis, and is a SN₂ displacement. The alkyl halide must be primary so the back side attack is not hindered, and the alkoxide ion must be formed with the most hindered group.
The mechanism can be seen in the attachment.
Ответ:
(See explanation for further details)
Explanation:
An insulated thermos indicates that there is no heat interactions between system and surroundings and there is a thermodynamic equilibrium between water and ice.
The mechanic equilibrium means that water and ice have the same pressure and thermal equilibrium means that water and ice have the same temperature. Given the existence of phase change, it means that phase with greater specific heat storage a major portion of heat. Water has a specific heat greater than in ice, which according to the First Law of Thermodynamics, there is less water than ice.