cherylmorton7302
19.02.2020 •
Chemistry
Chemists studied the formation of phosgene by sealing 0.96 atm of carbon monoxide and 1.15 atm of chlorine in a reactor at a certain temperature. The pressure dropped smoothly to 1.47 atm as the system reached equilbrium. Calculate Kp (in atm-1) for CO(g) + Cl2(g) ↔ COCl2(g)
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Ответ:
3.9
Explanation:
Let's consider the following reaction at equilibrium.
CO(g) + Cl₂(g) ↔ COCl₂(g)
We can find the pressures at equilibrium using an ICE chart.
CO(g) + Cl₂(g) ↔ COCl₂(g)
I 0.96 1.15 0
C -x -x +x
E 0.96-x 1.15-x x
The sum of the partial pressures is equal to the total pressure.
pCO + pCl₂ + pCOCl₂ = 1.47
(0.96-x) + (1.15-x) + x = 1.47
2.11 - x = 1.47
x = 0.64
The pressures at equilibrium are:
pCO = 0.96 - x = 0.32 atm
pCl₂ = 1.15 - x = 0.51 atm
pCOCl₂ = x = 0.64 atm
The pressure equilibrium constant (Kp) is:
Kp = pCOCl₂ / pCO × pCl₂
Kp = 0.64 / 0.32 × 0.51
Kp = 3.9
Ответ: